Lab Notes Gems & Gemology, Spring 2018, Vol. 54, No. 1

Fracture-Filled Diamond with "Rainbow" Flash Effect


Diamond before and after filling large fractures.
Figure 1. Large fractures in this diamond are exposed in high relief before treatment (left). After the fractures are filled, the same stone has a much improved apparent clarity (right). Photos by John I. Koivula.

A loose diamond submitted for a diamond grading report is evaluated and given a grade on a scale relative to each value factor. Clarity, defined as a diamond’s relative freedom from inclusions or blemishes, is graded on a scale of Flawless (least included) to I3 (most included). The most common inclusions in diamond are crystals, which are contained entirely within the stone, and fractures—also known as feathers—which are surface reaching. Various clarity treatments exist to mask or remove undesirable inclusions because high-clarity diamonds are considered more valuable. Some diamond clarity treatments are permanent, while others are not and may change drastically in appearance with time or improper care. For this reason, GIA does not issue grading reports for diamonds that have been treated with unstable, non-permanent treatments. Acceptable treatments such as laser drilling and internal laser drilling are always clearly disclosed on grading reports.

The classic flash effect is pink in darkfield and green in brightfield lighting.
Figure 2. The classic flash effect appearance: a pink flash in darkfield lighting (left) and a complementary green flash in brightfield lighting (right). Photos by John I. Koivula.

One such unstable treatment is fracture filling. Large, deep fractures in a diamond will often appear white or reflective due to the difference in the refractive index of the diamond and the air within the fracture. In an effort to disguise this, a substance with a refractive index similar to diamond’s, such as highly refractive lead glass, is introduced into surface-reaching fractures to reduce the interference of air (figure 1). Several telltale signs, such as the flash effect, typically reveal the presence of a filled fracture. The classic flash effect displays a vivid pink color in darkfield illumination and a complementary green color in brightfield illumination (figure 2). In a different orientation in brightfield lighting, a filled fracture can also appear bright blue.

Fracture-filled square modified brilliant cut diamond.
Figure 3. A face-up view of the near-colorless 1.21 ct fracture-filled square modified brilliant cut. Photo by Robison McMurtry.

A 1.21 ct near-colorless square modified brilliant diamond was recently submitted to GIA’s Carlsbad laboratory for a diamond grading report (figure 3). It was rejected for grading after examination revealed a large filled fracture. Interestingly, the flash effect looked noticeably different from the classic appearance described above. Rather than flashing a single color in darkfield lighting and a single complementary color in brightfield lighting, this filled fracture flashed multiple colors in darkfield and multiple complementary colors in brightfield (figure 4). The unusual effect may be due to a difference in ingredients used to manufacture the filling material. To the untrained eye, it could easily be mistaken for the natural iridescence very commonly seen in unfilled fractures. However, such iridescence typically appears when the viewing angle is nearly perpendicular to the fracture, while the flash effect is most visible when the viewing angle is nearly parallel to the plane of the fracture. In addition to the “rainbow” flash effect, this filled fracture showed a dendritic pattern at the fracture opening that is caused by air pockets in the filling substance (figure 5). This pattern is characteristic of incomplete fracture filling (J.I. Koivula, The MicroWorld of Diamonds, Gemworld International, Inc., Northbrook, Illinois, 2000, pp. 106–108) and provides further evidence of the treatment.

Multicolored
Figure 4. When viewed nearly parallel to the plane of the fracture, this filled fracture exhibits a multicolored “rainbow” flash effect in both darkfield illumination (left) and brightfield illumination (right), as opposed to a classic single-color flash effect. Photomicrographs by Nathan Renfro; field of view 2.21 mm.
Dendritic pattern (and its mirror reflection) at the opening of the diamond's fracture.
Figure 5. In addition to a “rainbow” flash effect, this filled fracture displays a dendritic pattern (and its mirror reflection) at the opening of the fracture. This pattern occurs as a result of incomplete fracture filling. Photomicrograph by Nathan Renfro; field of view 1.83 mm.

Hollie McBride is a staff gemologist at GIA in Carlsbad, California.