An Introduction to Simulants or Imitation Gem Materials


Colorless and pinkish purple CZ
Cubic zirconia can be produced in large sizes and in different colors. These colorless and pinkish purple CZ are, from left to right, 44.49 carats, 29.86 carats and 54.60 carats. Photo: Tino Hammid. Courtesy: Pamela Welborn

The jewelry industry uses the term “simulant” to refer to materials, such as CZ, that look like another gem and are used as its substitute but have very different chemical composition, crystal structure and optical and physical properties. These simulants, also known as imitations or substitutes, can be natural or manmade.

Man-made simulants

Synthetic cubic zirconia (CZ) – Numerous gems have been used as diamond imitations throughout history, but synthetic CZ has surpassed them all in popularity.

Introduced in the late 1970s, CZ is made through placing powdered zirconium oxide is inside a metal chamber and heating it to its melting point. The melt is then slowly moved away from its heat source, so that crystals grow at the bottom of the melt until the whole melt has solidified.

CZ has a Moh’s hardness of 8.5. That means it is a hard and durable gem although not as hard as diamond. Most CZ can be described as colorless, and most have high clarity with minute, if any, imperfections. CZ will, however, yellow in color over time. CZ has slightly more fire but less brilliance than diamond.

Cubic zirconia can be produced in almost any color. Pink and yellow CZs can be used as convincing pink or yellow diamond imitations. Other color CZs make good imitations of darker red, purple, blue, green or black gemstones.

Prevalence: common

700 cart light blue CZ stone
This blue CZ is a whopping 700 carats and has been faceted to have 722 facets. Photo: Robert Weldon. Courtesy: Victor Tuzlukov
Rough and faceted cubic zirconia
These faceted cubic zirconia show bright, broad flashes of fire. Courtesy: Robert Weldon/ GIA

Synthetic moissanite – Colorless synthetic moissanite became popular as a diamond imitation in the late 1990s and has become a very popular engagement ring stone due to its brilliance, intense fire and durability.

Moissanite can be colorless to near colorless. Its value often depends on its degree of colorlessness. Moissanite tends to have a few more inclusions than CZ, with clarity that could be described as having minor, if any, imperfections. It has a hardness of 9.25 on the Moh’s scale, which makes it very hard and durable, although not as hard as diamond. 

Moissanite has more than twice the fire of diamond and slightly more brilliance. In large sizes, one carat or above, its intense fire may give it away as a non-diamond gem. In very large sizes, its display of extreme fire is sometimes called the “disco ball” effect.

It is also different from diamond visually in that it is doubly refractive, so viewers will see a double image of its back facets. This means the inside of the moissanite may appear blurry. Some moissanites look slightly yellow or gray when viewed at certain angles.

Moissanite can come in colors such as yellow, black and blue and can be used as colored diamond substitutes.

Prevalence: increasingly common

Moissanite stone
Moissanites have slightly more brilliance than diamond and more than twice the fire. Photo: Robert Weldon/GIA
27.15 carat bluish green synthetic mossanite
Synthetic moissanite can come in different colors. This 27.15 carat specimen is bluish green. Photo: Robert Weldon. Courtesy: Victor Tuzlukov

Synthetic spinel synthetic spinel is often used as a simulant because it can mimic the look of many different natural gems (such as sapphire, zircon, aquamarine and peridot), depending on its color. Its accurate reproduction of a wide variety of colors makes it a common choice for imitation birthstone jewelry.

Prevalence: common  

Synthetic Spinel
This group of synthetic spinel boules and cut stones illustrates how this man made material can be made to look like other gemstones, such as ruby and various colors of sapphires.

Synthetic rutile synthetic rutile was introduced in the late 1940s and used as an early diamond simulant. Made by the flame-fusion method, it is nearly colorless with a slight yellowish tint, but it can be made in a variety of colors by doping (adding chemicals during the growth process).

Prevalence: rare

 

 

Natural Diamond and Synthetic Rutile
Natural diamond (left), and various diamond simulants: (inner left to right) synthetic rutile, gadolinium gallium garnet (or GGG), synthetic spinel, strontium titanate, synthetic corundum, yittrium aluminum garnet (or YAG), and colorless zircon.

Strontium titanate – this colorless manmade material became a popular diamond simulant in the 1950s. However, its dispersion (the optical property that creates fire in a faceted gemstone) is over four times greater than diamond. Strontium titanate is most often produced by the flame-fusion method and can be made in colors, such as dark red and brown, by adding certain chemicals during the growth process.

Prevalence: rare

YAG and GGG – several manmade materials have been used as diamond simulants over the years. In the 1960s, yttrium aluminum garnet (YAG) and its “cousin” gadolinium gallium garnet (GGG) joined classic simulants like glass, natural zircon, and colorless synthetic spinel. YAG and GGG are also available in a variety of colors.

Prevalence: rare

YAG
Yittrium aluminum garnet (or YAG) can be manufactured in a variety of colors such as those seen here. The colorless crystal is used as uncut material to fashion diamond simulants.

Glass – manufactured glass is an age-old gem imitation that is still used today. Since glass can be manufactured in virtually any color, this makes it a popular substitute for many gems. Although it is less brilliant, glass is used to imitate stones like amethyst, aquamarine, and peridot. It can also be made to look like natural phenomenal gems, like tiger’s eye and opal, and fused layers of glass can imitate the look of agate, malachite, or tortoise shell.

Prevalence: common

Glass Malachite and Rutilated Quartz
Glass, such as this material, can be made to look like a variety of gemstones; in this case glass makes a convincing substitute for malachite (left), and rutilated quartz (right).
Opal Simulants, slocum stones
A glass material known as “slocum stone” can mimic the appearance of opal.

Plastic plastic is often used to imitate gemstones in inexpensive fashion jewelry. However, this modern manmade substance has also been manipulated into convincing imitations of organic gems like amber, pearl, and coral, or aggregate materials like jade, turquoise and lapis. Plastic is not a durable imitation, so special care must be taken to prevent damage.

Prevalence: common

Quench crackled quartz – Natural colorless quartz can sometimes be subjected to thermal shock, known as “quench crackling.”  The colorless material is first heated, and then subjected to quenching in a cold, liquid solution—such as water. The sudden contraction causes the material to develop a series of cracks that radiate throughout. Because these are surface-reaching fractures, the quartz can then be subjected to additional immersion in a dye solution, allowing the fractures to be filled with colored liquid. This makes a convincing simulant to such natural gems as emerald, ruby and sapphire, although the fractured and dyed appearance can quickly be seen under the microscope.

Prevalence: occasional 

Quench Crackled Quartz
Colorless quartz can be subjected to thermal shock that creates a series of tiny fractures throughout the stone. Dye is then introduced, causing the material to simulate many different kinds of gems, in this case—emerald and ruby.

Ceramic beads – you’ve probably heard the term “ceramic” applied to clay pottery. In general, a ceramic can be any product made from a nonmetallic material by firing at high temperature. Two popular non-faceted gems, imitation turquoise and imitation lapis lazuli, are produced by ceramic processes. During this process, a finely ground powder is heated and sometimes placed under pressure to recrystallize and harden to produce a fine-grained solid material.

Prevalence: occasional

Imitation turquoise – the cool blues and greens of turquoise have attracted people for centuries. More than 5,000 years ago, Egyptian pharaohs first adorned themselves with turquoise. The familiar gem is a microcrystalline aggregate that often features attractive, vein-like inclusions of host rock known as matrix. In the early 1970s, Gilson introduced an imitation turquoise as well as an imitation lapis.

Prevalence: occasional   

Gilson Imitation Turquois  and Lapis Lazuli
Gilson imitation turquoise and lapis lazuli make convincing substitutes for their counterparts found in nature.

Imitation lapis lazuli dark blue lapis, treasured by ancient civilizations, has been mined in Afghanistan for more than 6,000 years. The gem is an aggregate of several different minerals. It sometimes contains gold-colored flecks of pyrite that can enhance its appeal. Gilson’s lapis is more accurately considered an imitation because it has some ingredients and physical properties that are different from natural lapis.

Prevalence: rare

Assembled Stones

When manufacturers glue or fuse two or more separate pieces of material together in the form of a faceted gemstone, the result is called an assembled or composite stone. The separate pieces can be natural or manmade. The flat surfaces that are glued together are parallel to the large table facet of the gem so as to impart a more uniform face-up color.

Doublet – a doublet consists of two joined segments.

Prevalence: common

Doublet
A doublet, such as this one, contains two joined portions of a gem that are held together by colorless glue, as a profile view of this material shows.

  

Triplet – a triplet has three segments, or two segments separated by a layer of colored cement.

Prevalence: common

Triplet
A triplet contains two or more segments of a gem, or different gems, that are joined by layers of glue. In a profile view, this image shows a thin seam of opal in the center that is backed by dyed black chalcedony, and is overlayed (the domed area) by a quartz cabochon.

Although doublets and triplets are used to imitate natural gems, assembled stones are not always imitations. This is the case with natural opal, which sometimes occurs in layers so thin that they need reinforcement to be sturdy enough for jewelry use. Black onyx, plastic, or natural matrix have served as the bottom layers of opal doublet or triplet cabochons. Opal triplets are topped with a transparent dome made of rock crystal, plastic, glass, or synthetic corundum.